anch

anch
50問 • 1年前
  • Reviewer
  • 通報

    問題一覧

  • 1

    GD-AES combines the advantages of ______________ and ____________.

    ICP-OES and XRF

  • 2

    Glow discharge optical emission spectrometry (GD-OES) is a widely used tool for fast measurements of _____ profiles.

    Depth

  • 3

    It is a technique in which the composition of elements in samples, mostly water-dissolved, can be determined using plasma and a spectrometer.

    Inductively Coupled Plasma Optical Emission Spectrometry

  • 4

    It is a technique capable of providing information about the elemental and isotopic composition of samples in situ from a few micrometers down to the sub-micron scale.

    Secondary Ion Mass Spectrometry

  • 5

    This technique is an ideal tool to investigate from the surface down to more than 150 microns with a depth resolution that can be as good as 1 nm.

    Glow Discharge Atomic Emission Spectrometry

  • 6

    This type of Plasma Emission Source has a distinct advantage; stability with varying sample matrices, a characteristic which is particularly valuable where the solvent contains a high concentration of dissolved solids.

    Direct Current Plasma Source

  • 7

    This type of Plasma Emission Source uses an ion source that consists of a torch that is surrounded by a radio frequency generator that ionises argon gas inside the torch to form a high-temperature (up to 10,000 K) plasma that can be used to ionise analytes.

    Inductively Coupled Plasma Torch

  • 8

    It is a part of the Plasma Emission Spectrometer which is used in the dispersion of the emitted radiation and in the presentation of the analytical signal.

    Both A and B

  • 9

    In Sample Introduction for Plasma Sources, sample solution is pumped by a peristaltic pump at a fixed rate and converted into an aerosol by a _________.

    Nebulizer

  • 10

    Plasma Emission Spectrometry is enormous and is most helpful in almost every field where ______analysis is carried out.

    Trace Element

  • 11

    An elemental analysis technology capable of detecting most of the periodic table of elements at milligram to nanogram levels per liter.

    Inductively Coupled Plasma Mass Spectrometry

  • 12

    Instrument that works on the principle of compound ionization and fragmentation (typically through the bombardment by electrons or selected ions), the physical separation of the charged fragments, and their detection.

    Mass Spectrometer

  • 13

    An analytical technique that can be used to measure elements at trace levels in biological fluids.

    Inductively Coupled Plasma Mass Spectrometry

  • 14

    Which part of the ICP Mass Spectrometer carries the argon (Ar) that forms the plasma?

    ICP torch

  • 15

    An ionised gas, consisting of positively-charged ions and free (unbound) electrons.

    Plasma

  • 16

    Principal Zone of Flames where combustion, atomization and thermal excitation occur.

    Both Inner Cone and Primary Reaction Zone (A and C)

  • 17

    Flame Emission Spectrometry is a particularly useful technique for the determination of volatile elements with high excitation energies such as the alkali and alkaline earth metals.

    False

  • 18

    FES Principle: Emission of electromagnetic radiation in the visible and infrared regions of the spectrum by atoms after electronic excitation in flames.

    False

  • 19

    This interference may arise from the close proximity of other emission lines or bands to the analyte line or by overlap with it.

    Spectral Interference

  • 20

    This interference occurs because of interaction with ground state atoms of the analyte in the cooler outer fringes of the flame (commonly encountered with easily ionized elements such as alkali metals and alkaline earths) and results in attenuation of the intensity of emission.

    Self Absorption

  • 21

    True or False: The principle of AAS is absorption of electromagnetic radiation in the visible and infrared regions of the spectrum by atoms resulting in changes in electronic structure.

    False

  • 22

    True or False: One disadvantage of AAS is that it is generally less sensitive than flame emission because the vast majority of atoms produced in the usual propane or air acetylene flame remain in the ground state available for light absorption.

    False

  • 23

    True or False: Doppler broadening results from the rapid motion of atoms as they emit or absorb radiation.

    True

  • 24

    The radiation emitted as a result of absorption (fluorescence) is measured, often at right angles to avoid measuring the source radiation.

    Emission

  • 25

    It is the characteristic of the atoms which have absorbed the primary radiation.

    Fluorescent Radiation

  • 26

    Part of AF Spectrometer that collects fluorescence radiation.

    Detection System

  • 27

    Generally employed for the routine analysis of specific elements.

    Filter based instruments

  • 28

    A wide range of energy transitions (wavelength) and consequently a continuum of X-ray emissions.

    White X-Ray

  • 29

    A fluorescent (or secondary) X-ray emitted from a sample when it is excited by a primary X-ray source.

    X-Ray Fluorescence

  • 30

    This X-Ray Emission method have a wide application in routine industrial analysis particularly in mineral processing and metallurgy.

    X-Ray Fluorescence

  • 31

    A quantitative analysis wherein excitation occurs when an electron residing in a low-energy molecular or atomic orbital is promoted to a higher-energy orbital.

    Visible and UV Spectrometry

  • 32

    Unsaturated organic functional groups that absorb in the ultraviolet or visible regions.

    chromophore

  • 33

    Saturated groups containing heteroatoms which modify the absorption due to a chromophore.

    auxochrome

  • 34

    The shortest wavelength (highest energy) emission, which arises from the transition to the lowestvibrational level in the ground electronic state.

    resonance fluorescence

  • 35

    A general term for relaxation in which radiation of a longer wavelength (lower energy) than that originally absorbed is reemitted.

    photoluminescence

  • 36

    For ___________, the complexity of the spectrum increases rapidly with the number of atoms N in the molecule.

    Polyatomic Molecule

  • 37

    The classical analogy of a vibrating ________ is that of two weights connected by a spring.

    Diatomic Molecule

  • 38

    Spectra are usually recorded as liquids, solids or in solution.

    Polyatomic Molecule

  • 39

    A __________ behaves rather differently in that the forces of internuclear repulsion arising when the bond is compressed build up rapidly whilst, on stretching, the bond weakens and may finally disrupt.

    Diatomic Molecule

  • 40

    Occurs if samples are exposed to the full power of an ultraviolet or visible source.

    Photochemical decomposition

  • 41

    Observed only if the chemical shift difference between the coupled groups is large compared to the coupling constant.

    First Order Spectrum

  • 42

    Chemical shifts between 13C nuclei in different chemical environments can differ by as much as 200 ppm whereas proton shift differences are seldom more than 10 ppm.

    Carbon 13 NMR

  • 43

    Allows only the coupling between 13C nuclei and protons directly bonded to them to be observed.

    Off Resonance Decoupling

  • 44

    Consists of irradiating the sample over a wide frequency range covering all the proton resonances in thesample.

    Noise Decoupling

  • 45

    Absorption bands arising from adjacent protons are split into multiplet peaks by a mutual interaction of the spins.

    Spin spin coupling

  • 46

    In __________, the sample is subjected to a series of single (several microseconds duration), high-power RF pulses of wide frequency range which excite all the nuclei of a particular element (isotope).

    Pulsed Fourier Transform NMR

  • 47

    Identifies the specific protons attached to each carbon-13 (1H–13C connectivities)

    Heteronuclear Chemical Shift Correlation Spectrometry

  • 48

    Provides proton-proton coupling information (1H– 1H connectivities).

    Homonuclear Correlation Spectroscopy

  • 49

    Identifies directly bonded 13C nuclei (13C– 13C connectivities) which allows the carbon skeleton of a compound to be elucidated.

    Incredible natural abundance double quantum transfer experiment

  • 50

    Correlated Spectroscopy is also known as

    Homonuclear Correlation Spectroscopy

  • PMLS

    PMLS

    Reviewer · 87問 · 2年前

    PMLS

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    87問 • 2年前
    Reviewer

    ANAPHY

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    Reviewer · 101問 · 2年前

    ANAPHY

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    101問 • 2年前
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    Anaphy P2

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    Anaphy P2

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    Reviewer · 44問 · 2年前

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    31問 • 2年前
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    hes p3

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    Reviewer · 20問 · 1年前

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    20問 • 1年前
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    Reviewer · 61問 · 1年前

    sjc l1

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    61問 • 1年前
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    bio lab1 pic

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    Reviewer · 18問 · 1年前

    bio lab1 pic

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    18問 • 1年前
    Reviewer

    sjc L2

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    Reviewer · 91問 · 1年前

    sjc L2

    sjc L2

    91問 • 1年前
    Reviewer

    Biostat L3

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    Reviewer · 63問 · 1年前

    Biostat L3

    Biostat L3

    63問 • 1年前
    Reviewer

    sjc L3&L4

    sjc L3&L4

    Reviewer · 53問 · 1年前

    sjc L3&L4

    sjc L3&L4

    53問 • 1年前
    Reviewer

    HIS L3

    HIS L3

    Reviewer · 67問 · 1年前

    HIS L3

    HIS L3

    67問 • 1年前
    Reviewer

    HIS L4

    HIS L4

    Reviewer · 33問 · 1年前

    HIS L4

    HIS L4

    33問 • 1年前
    Reviewer

    HIS L5

    HIS L5

    Reviewer · 36問 · 1年前

    HIS L5

    HIS L5

    36問 • 1年前
    Reviewer

    HIS L3

    HIS L3

    Reviewer · 35問 · 1年前

    HIS L3

    HIS L3

    35問 • 1年前
    Reviewer

    PSTM L3-L5

    PSTM L3-L5

    Reviewer · 57問 · 1年前

    PSTM L3-L5

    PSTM L3-L5

    57問 • 1年前
    Reviewer

    P1 Reviewer

    P1 Reviewer

    Reviewer · 43問 · 1年前

    P1 Reviewer

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    43問 • 1年前
    Reviewer

    P2

    P2

    Reviewer · 42問 · 1年前

    P2

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    42問 • 1年前
    Reviewer

    CPH P2

    CPH P2

    Reviewer · 61問 · 1年前

    CPH P2

    CPH P2

    61問 • 1年前
    Reviewer

    P2

    P2

    Reviewer · 60問 · 1年前

    P2

    P2

    60問 • 1年前
    Reviewer

    P2 Mod

    P2 Mod

    Reviewer · 60問 · 1年前

    P2 Mod

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    60問 • 1年前
    Reviewer

    ANCH P2

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    Reviewer · 70問 · 1年前

    ANCH P2

    ANCH P2

    70問 • 1年前
    Reviewer

    ANCH P2 MOD

    ANCH P2 MOD

    Reviewer · 60問 · 1年前

    ANCH P2 MOD

    ANCH P2 MOD

    60問 • 1年前
    Reviewer

    CPH

    CPH

    Reviewer · 30問 · 1年前

    CPH

    CPH

    30問 • 1年前
    Reviewer

    HIS

    HIS

    Reviewer · 47問 · 1年前

    HIS

    HIS

    47問 • 1年前
    Reviewer

    CFU ANCH P1-P3

    CFU ANCH P1-P3

    Reviewer · 80問 · 1年前

    CFU ANCH P1-P3

    CFU ANCH P1-P3

    80問 • 1年前
    Reviewer

    ANCH P2 Terms

    ANCH P2 Terms

    Reviewer · 40問 · 1年前

    ANCH P2 Terms

    ANCH P2 Terms

    40問 • 1年前
    Reviewer

    BIOSTAT FINALS (1)

    BIOSTAT FINALS (1)

    Reviewer · 100問 · 1年前

    BIOSTAT FINALS (1)

    BIOSTAT FINALS (1)

    100問 • 1年前
    Reviewer

    BIOSTAT FINALS (2)

    BIOSTAT FINALS (2)

    Reviewer · 84問 · 1年前

    BIOSTAT FINALS (2)

    BIOSTAT FINALS (2)

    84問 • 1年前
    Reviewer

    BIOSTAT FORMULA

    BIOSTAT FORMULA

    Reviewer · 14問 · 1年前

    BIOSTAT FORMULA

    BIOSTAT FORMULA

    14問 • 1年前
    Reviewer

    CFU CPH 1-5

    CFU CPH 1-5

    Reviewer · 94問 · 1年前

    CFU CPH 1-5

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    94問 • 1年前
    Reviewer

    CFU CPH 6-16

    CFU CPH 6-16

    Reviewer · 80問 · 1年前

    CFU CPH 6-16

    CFU CPH 6-16

    80問 • 1年前
    Reviewer

    CFU CPH 17-23

    CFU CPH 17-23

    Reviewer · 40問 · 1年前

    CFU CPH 17-23

    CFU CPH 17-23

    40問 • 1年前
    Reviewer

    CFU HIS P1

    CFU HIS P1

    Reviewer · 60問 · 1年前

    CFU HIS P1

    CFU HIS P1

    60問 • 1年前
    Reviewer

    CFU HIS P2

    CFU HIS P2

    Reviewer · 60問 · 1年前

    CFU HIS P2

    CFU HIS P2

    60問 • 1年前
    Reviewer

    CFU HIS P3

    CFU HIS P3

    Reviewer · 47問 · 1年前

    CFU HIS P3

    CFU HIS P3

    47問 • 1年前
    Reviewer

    BIOSTAT FORMULA

    BIOSTAT FORMULA

    Reviewer · 14問 · 1年前

    BIOSTAT FORMULA

    BIOSTAT FORMULA

    14問 • 1年前
    Reviewer

    Mod 1-7

    Mod 1-7

    Reviewer · 83問 · 1年前

    Mod 1-7

    Mod 1-7

    83問 • 1年前
    Reviewer

    Mod 1

    Mod 1

    Reviewer · 15問 · 1年前

    Mod 1

    Mod 1

    15問 • 1年前
    Reviewer

    Mod 2

    Mod 2

    Reviewer · 15問 · 1年前

    Mod 2

    Mod 2

    15問 • 1年前
    Reviewer

    Mod 3

    Mod 3

    Reviewer · 15問 · 1年前

    Mod 3

    Mod 3

    15問 • 1年前
    Reviewer

    Mod 4

    Mod 4

    Reviewer · 11問 · 1年前

    Mod 4

    Mod 4

    11問 • 1年前
    Reviewer

    Mod 6

    Mod 6

    Reviewer · 15問 · 1年前

    Mod 6

    Mod 6

    15問 • 1年前
    Reviewer

    Mod 1-6

    Mod 1-6

    Reviewer · 40問 · 1年前

    Mod 1-6

    Mod 1-6

    40問 • 1年前
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    Mod 7

    Mod 7

    Reviewer · 10問 · 1年前

    Mod 7

    Mod 7

    10問 • 1年前
    Reviewer

    Mod 1

    Mod 1

    Reviewer · 5問 · 1年前

    Mod 1

    Mod 1

    5問 • 1年前
    Reviewer

    Mod 2

    Mod 2

    Reviewer · 10問 · 1年前

    Mod 2

    Mod 2

    10問 • 1年前
    Reviewer

    Mod 3

    Mod 3

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    Mod 3

    Mod 3

    5問 • 1年前
    Reviewer

    Mod 4

    Mod 4

    Reviewer · 5問 · 1年前

    Mod 4

    Mod 4

    5問 • 1年前
    Reviewer

    Mod 5

    Mod 5

    Reviewer · 5問 · 1年前

    Mod 5

    Mod 5

    5問 • 1年前
    Reviewer

    Mod 6

    Mod 6

    Reviewer · 10問 · 1年前

    Mod 6

    Mod 6

    10問 • 1年前
    Reviewer

    Mod 1-7

    Mod 1-7

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    Mod 1-7

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    95問 • 1年前
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    Mod 1

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    12問 • 1年前
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    Mod 2

    Mod 2

    Reviewer · 15問 · 1年前

    Mod 2

    Mod 2

    15問 • 1年前
    Reviewer

    Mod 3

    Mod 3

    Reviewer · 15問 · 1年前

    Mod 3

    Mod 3

    15問 • 1年前
    Reviewer

    Mod 4

    Mod 4

    Reviewer · 15問 · 1年前

    Mod 4

    Mod 4

    15問 • 1年前
    Reviewer

    Mod 5

    Mod 5

    Reviewer · 15問 · 1年前

    Mod 5

    Mod 5

    15問 • 1年前
    Reviewer

    Mod 6

    Mod 6

    Reviewer · 10問 · 1年前

    Mod 6

    Mod 6

    10問 • 1年前
    Reviewer

    Mod 7

    Mod 7

    Reviewer · 15問 · 1年前

    Mod 7

    Mod 7

    15問 • 1年前
    Reviewer

    Mod 1

    Mod 1

    Reviewer · 15問 · 1年前

    Mod 1

    Mod 1

    15問 • 1年前
    Reviewer

    Mod 2

    Mod 2

    Reviewer · 15問 · 1年前

    Mod 2

    Mod 2

    15問 • 1年前
    Reviewer

    Mod 3

    Mod 3

    Reviewer · 13問 · 1年前

    Mod 3

    Mod 3

    13問 • 1年前
    Reviewer

    Mod 1

    Mod 1

    Reviewer · 9問 · 1年前

    Mod 1

    Mod 1

    9問 • 1年前
    Reviewer

    Mod 7

    Mod 7

    Reviewer · 10問 · 1年前

    Mod 7

    Mod 7

    10問 • 1年前
    Reviewer

    Mod 6

    Mod 6

    Reviewer · 10問 · 1年前

    Mod 6

    Mod 6

    10問 • 1年前
    Reviewer

    Mod 1

    Mod 1

    Reviewer · 10問 · 1年前

    Mod 1

    Mod 1

    10問 • 1年前
    Reviewer

    Mod 5

    Mod 5

    Reviewer · 7問 · 1年前

    Mod 5

    Mod 5

    7問 • 1年前
    Reviewer

    Mod 2

    Mod 2

    Reviewer · 10問 · 1年前

    Mod 2

    Mod 2

    10問 • 1年前
    Reviewer

    Mod 4

    Mod 4

    Reviewer · 10問 · 1年前

    Mod 4

    Mod 4

    10問 • 1年前
    Reviewer

    Mod 7

    Mod 7

    Reviewer · 10問 · 1年前

    Mod 7

    Mod 7

    10問 • 1年前
    Reviewer

    Mod 5

    Mod 5

    Reviewer · 10問 · 1年前

    Mod 5

    Mod 5

    10問 • 1年前
    Reviewer

    Mod 6

    Mod 6

    Reviewer · 10問 · 1年前

    Mod 6

    Mod 6

    10問 • 1年前
    Reviewer

    Mod 2

    Mod 2

    Reviewer · 5問 · 1年前

    Mod 2

    Mod 2

    5問 • 1年前
    Reviewer

    Mod 3

    Mod 3

    Reviewer · 10問 · 1年前

    Mod 3

    Mod 3

    10問 • 1年前
    Reviewer

    Mod 4

    Mod 4

    Reviewer · 9問 · 1年前

    Mod 4

    Mod 4

    9問 • 1年前
    Reviewer

    Mod 5

    Mod 5

    Reviewer · 9問 · 1年前

    Mod 5

    Mod 5

    9問 • 1年前
    Reviewer

    Lab Management

    Lab Management

    Reviewer · 60問 · 1年前

    Lab Management

    Lab Management

    60問 • 1年前
    Reviewer

    Biochemistry

    Biochemistry

    Reviewer · 50問 · 1年前

    Biochemistry

    Biochemistry

    50問 • 1年前
    Reviewer

    Cytogenetics

    Cytogenetics

    Reviewer · 50問 · 1年前

    Cytogenetics

    Cytogenetics

    50問 • 1年前
    Reviewer

    問題一覧

  • 1

    GD-AES combines the advantages of ______________ and ____________.

    ICP-OES and XRF

  • 2

    Glow discharge optical emission spectrometry (GD-OES) is a widely used tool for fast measurements of _____ profiles.

    Depth

  • 3

    It is a technique in which the composition of elements in samples, mostly water-dissolved, can be determined using plasma and a spectrometer.

    Inductively Coupled Plasma Optical Emission Spectrometry

  • 4

    It is a technique capable of providing information about the elemental and isotopic composition of samples in situ from a few micrometers down to the sub-micron scale.

    Secondary Ion Mass Spectrometry

  • 5

    This technique is an ideal tool to investigate from the surface down to more than 150 microns with a depth resolution that can be as good as 1 nm.

    Glow Discharge Atomic Emission Spectrometry

  • 6

    This type of Plasma Emission Source has a distinct advantage; stability with varying sample matrices, a characteristic which is particularly valuable where the solvent contains a high concentration of dissolved solids.

    Direct Current Plasma Source

  • 7

    This type of Plasma Emission Source uses an ion source that consists of a torch that is surrounded by a radio frequency generator that ionises argon gas inside the torch to form a high-temperature (up to 10,000 K) plasma that can be used to ionise analytes.

    Inductively Coupled Plasma Torch

  • 8

    It is a part of the Plasma Emission Spectrometer which is used in the dispersion of the emitted radiation and in the presentation of the analytical signal.

    Both A and B

  • 9

    In Sample Introduction for Plasma Sources, sample solution is pumped by a peristaltic pump at a fixed rate and converted into an aerosol by a _________.

    Nebulizer

  • 10

    Plasma Emission Spectrometry is enormous and is most helpful in almost every field where ______analysis is carried out.

    Trace Element

  • 11

    An elemental analysis technology capable of detecting most of the periodic table of elements at milligram to nanogram levels per liter.

    Inductively Coupled Plasma Mass Spectrometry

  • 12

    Instrument that works on the principle of compound ionization and fragmentation (typically through the bombardment by electrons or selected ions), the physical separation of the charged fragments, and their detection.

    Mass Spectrometer

  • 13

    An analytical technique that can be used to measure elements at trace levels in biological fluids.

    Inductively Coupled Plasma Mass Spectrometry

  • 14

    Which part of the ICP Mass Spectrometer carries the argon (Ar) that forms the plasma?

    ICP torch

  • 15

    An ionised gas, consisting of positively-charged ions and free (unbound) electrons.

    Plasma

  • 16

    Principal Zone of Flames where combustion, atomization and thermal excitation occur.

    Both Inner Cone and Primary Reaction Zone (A and C)

  • 17

    Flame Emission Spectrometry is a particularly useful technique for the determination of volatile elements with high excitation energies such as the alkali and alkaline earth metals.

    False

  • 18

    FES Principle: Emission of electromagnetic radiation in the visible and infrared regions of the spectrum by atoms after electronic excitation in flames.

    False

  • 19

    This interference may arise from the close proximity of other emission lines or bands to the analyte line or by overlap with it.

    Spectral Interference

  • 20

    This interference occurs because of interaction with ground state atoms of the analyte in the cooler outer fringes of the flame (commonly encountered with easily ionized elements such as alkali metals and alkaline earths) and results in attenuation of the intensity of emission.

    Self Absorption

  • 21

    True or False: The principle of AAS is absorption of electromagnetic radiation in the visible and infrared regions of the spectrum by atoms resulting in changes in electronic structure.

    False

  • 22

    True or False: One disadvantage of AAS is that it is generally less sensitive than flame emission because the vast majority of atoms produced in the usual propane or air acetylene flame remain in the ground state available for light absorption.

    False

  • 23

    True or False: Doppler broadening results from the rapid motion of atoms as they emit or absorb radiation.

    True

  • 24

    The radiation emitted as a result of absorption (fluorescence) is measured, often at right angles to avoid measuring the source radiation.

    Emission

  • 25

    It is the characteristic of the atoms which have absorbed the primary radiation.

    Fluorescent Radiation

  • 26

    Part of AF Spectrometer that collects fluorescence radiation.

    Detection System

  • 27

    Generally employed for the routine analysis of specific elements.

    Filter based instruments

  • 28

    A wide range of energy transitions (wavelength) and consequently a continuum of X-ray emissions.

    White X-Ray

  • 29

    A fluorescent (or secondary) X-ray emitted from a sample when it is excited by a primary X-ray source.

    X-Ray Fluorescence

  • 30

    This X-Ray Emission method have a wide application in routine industrial analysis particularly in mineral processing and metallurgy.

    X-Ray Fluorescence

  • 31

    A quantitative analysis wherein excitation occurs when an electron residing in a low-energy molecular or atomic orbital is promoted to a higher-energy orbital.

    Visible and UV Spectrometry

  • 32

    Unsaturated organic functional groups that absorb in the ultraviolet or visible regions.

    chromophore

  • 33

    Saturated groups containing heteroatoms which modify the absorption due to a chromophore.

    auxochrome

  • 34

    The shortest wavelength (highest energy) emission, which arises from the transition to the lowestvibrational level in the ground electronic state.

    resonance fluorescence

  • 35

    A general term for relaxation in which radiation of a longer wavelength (lower energy) than that originally absorbed is reemitted.

    photoluminescence

  • 36

    For ___________, the complexity of the spectrum increases rapidly with the number of atoms N in the molecule.

    Polyatomic Molecule

  • 37

    The classical analogy of a vibrating ________ is that of two weights connected by a spring.

    Diatomic Molecule

  • 38

    Spectra are usually recorded as liquids, solids or in solution.

    Polyatomic Molecule

  • 39

    A __________ behaves rather differently in that the forces of internuclear repulsion arising when the bond is compressed build up rapidly whilst, on stretching, the bond weakens and may finally disrupt.

    Diatomic Molecule

  • 40

    Occurs if samples are exposed to the full power of an ultraviolet or visible source.

    Photochemical decomposition

  • 41

    Observed only if the chemical shift difference between the coupled groups is large compared to the coupling constant.

    First Order Spectrum

  • 42

    Chemical shifts between 13C nuclei in different chemical environments can differ by as much as 200 ppm whereas proton shift differences are seldom more than 10 ppm.

    Carbon 13 NMR

  • 43

    Allows only the coupling between 13C nuclei and protons directly bonded to them to be observed.

    Off Resonance Decoupling

  • 44

    Consists of irradiating the sample over a wide frequency range covering all the proton resonances in thesample.

    Noise Decoupling

  • 45

    Absorption bands arising from adjacent protons are split into multiplet peaks by a mutual interaction of the spins.

    Spin spin coupling

  • 46

    In __________, the sample is subjected to a series of single (several microseconds duration), high-power RF pulses of wide frequency range which excite all the nuclei of a particular element (isotope).

    Pulsed Fourier Transform NMR

  • 47

    Identifies the specific protons attached to each carbon-13 (1H–13C connectivities)

    Heteronuclear Chemical Shift Correlation Spectrometry

  • 48

    Provides proton-proton coupling information (1H– 1H connectivities).

    Homonuclear Correlation Spectroscopy

  • 49

    Identifies directly bonded 13C nuclei (13C– 13C connectivities) which allows the carbon skeleton of a compound to be elucidated.

    Incredible natural abundance double quantum transfer experiment

  • 50

    Correlated Spectroscopy is also known as

    Homonuclear Correlation Spectroscopy