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  • 問題数 100 • 7/7/2024

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    問題一覧

  • 1

    The electronic configuration of cu2+ ion is :The electronic configuration of cu2+ ion is :

    3d9 4s0

  • 2

    Which is the correct order for the listed atoms with increase of the atomic radius :Which is the correct order for the listed atoms with increase of the atomic radius :

    B , Be , Li , Na

  • 3

    A π-bond is the result of :A π-bond is the result of :

    overlap of two p-orbitals

  • 4

    What is the ground electronic state of Mn 2+

    1s2 2s2 2p6 3s2 3p6 3d5

  • 5

    The capability of alcohols to form intermolecular hydrogen bonds leads to:

    decreased vapor pressure

  • 6

    Which is the correct order of halogen ions with decrease of reductive properties?

    I- , Br-, Cl- , F-

  • 7

    The the element X has an atomic number of 8 and a mass number of 17. The atoms of this element contain :

    9 neutrons

  • 8

    Which of the following elements exists as a monoatomic gas under standard conditions?

    neon

  • 9

    Hydrogen may NOT be obtained by

    interaction of cooper and nitric acid

  • 10

    The industrial process of production of sulphuric acid includes the following stages

    production of SO2 , catalytic oxidation to SO3 and interaction of SO3 with water

  • 11

    Mark the line which includes only salts, whose water solutions are basic:

    Sodium carbonate, potassium sulphide, potassium phosphate

  • 12

    Chlorine CANNOT be obtained

    By interaction of sodium chloride with concentrated sulphuric acid

  • 13

    Increasing the pressure in an equilibrium system containing gas molecules leads to the withdrawal of the chemical equilibrium in the direction of the reaction

    Flowing with decrease in the gas molecules number

  • 14

    At two fold increase of the pressure the rates of the straight and the reverse reaction of the system A(g) + 2B(g) = AB2(g) are changed accordingly

    Straight -increased 8 times, reverse-increased 2 times

  • 15

    10 moles of benzene contain

    6.02*10 *24 benzene molecules

  • 16

    In oxidative -reduction processes the reducer

    Increases its oxidation number

  • 17

    In oxidative-reductive processes the oxidising agent

    Decreases its oxidation number

  • 18

    Oxidative reductive processes could be

    All answers are correct

  • 19

    The oxidation number for hydrogen in NaH is

    -1

  • 20

    When nonspontaneous redox reactions occure by use of a direct electric current, the process is called

    Electrolysis

  • 21

    The hydroxonium ion is represented as

    H3O+

  • 22

    The chemical elements presented are arranged in order of decrease in their reactivity according to the activity series of metals. Ca , Na , Mg , Zn , Fe , H , Cu , Hg , Ag , Au Which is the best reducing agent ,which is oxidised the easiest?

    Ca

  • 23

    The cathode in an electrochemical cell is the electrode that is

    The electrode where reduction takes place

  • 24

    With addition of a catalyst to a system at equilibrium

    The forward and reverse reactions rates are increased equally

  • 25

    The chemical reaction 2Cl2 + H2O —><—O2 + 4HCl is in chemical equilibrium. The rate of the forward reaction is

    Equal to the rate of the reverse reaction

  • 26

    Hydrogen peroxide is easily decomposed to water and oxygen according to the reaction 2H2O2–> 2H2O + O2 . It’s ability is increased in the presence of H3PO4

    H3PO4 negative Catalyst and the catalysis is homogenous

  • 27

    How many times the rate of the reaction 2NO + O2 —> 2NO2 will increase if the concentration of all substances is increased two times

    8 times

  • 28

    The reaction rate of a multistage reaction is determined by

    The rate of the slowest stage

  • 29

    The chemical elements of group IB have

    1 electron in their outermost electronic shell

  • 30

    The isotopes

    Occupy one and the same location in the periodic table of elements

  • 31

    The principal quantum number

    All answers are correct

  • 32

    There azimuthal quantum number

    All answers are correct

  • 33

    Finding the permitted states of electrons

    Is done with the help of Pauli’s principal

  • 34

    Which statement for an equilibrium system is true?

    The rate of the straight and reverse reaction are equal

  • 35

    The equilibrium constant of a given reaction depends on

    The nature of the reactants and the temperature

  • 36

    Henry’s law is Is followed when

    There is no chemical interaction between the dissolving gas and the solvent

  • 37

    The Tyndall effect is due to

    Dispersion of the light

  • 38

    Indicate the wrong statement

    The equilibrium constant depends on the presence of catalysts

  • 39

    How the degree of electrolyte dissociation(a) and the dissociation constant (KD)of solution of HCN will change upon increasing its concentration

    a decreases, KD is not changed

  • 40

    The foam is a system of

    Gas dispersed in liquid

  • 41

    If to an aqueous solution of HCN is added NaOH the degree of electrolyte dissociation (a) for HCN

    Increases

  • 42

    What is the pH value of 0.01M solution of HCl

    2

  • 43

    An aqueous solution of a salt has pH 9. Thus it follows that this is a salt of :

    Weak acid and strong base

  • 44

    The maximal oxidation state of the atoms of chemical elements is equal to

    The number of the group in which is the element in the periodic table

  • 45

    A colloid of Al(OH)3 with positively charged granules coagulates with the addition of a certain amount of electrolyte. Which of the listed electrolytes, on equal terms( concentration ,volume) will cause the fastest coagulation?

    Al2(SO4)3

  • 46

    Which of the presented reactions is NOT oxidative-reductive ?

    Interaction of calcium hydroxide with sulphuric acid

  • 47

    For manufacture of nitric acid two oxides are used :

    NO and NO2

  • 48

    On combustion of ammonia, the nitrogen is converted to:

    free N2

  • 49

    Which statement about the four quantum numbers which describe electrons in atoms is INCORRECT?

    l= subsidiary (or azimuthal) quantum number, l=1,2,3,…,(n+1)

  • 50

    In reaction A has an activation energy of 250 kJ And reaction Bhas an activation energy of 100 kJ which of the following statements MUST be correct?

    At the same temperature the rate of reaction B is greater than the rate of reaction A.

  • 51

    In which row against the type of the chemical bond is a suitable listed example?

    Covalent polar, simple bond-H2O

  • 52

    The crystalline substance X is very soluble in water, it melts when heated, and its (aqueous solution does NOT conduct electricity. Substance X can be:

    Glucose

  • 53

    In which pair of substances is the oxidation number of carbon -4 and +4, respectively?

    CH4, CaCO3

  • 54

    Which of the following substances is the electrolyte?

    CH3COOH

  • 55

    At constant temperature an aqueous solution of glucose with concentration of 1mol/L compared to water has

    Higher osmotic pressure

  • 56

    In which of the indicated pairs there is NO correspondence between the chemical formula and the name of the substance?

    Na2O2-disodium oxide

  • 57

    Interaction does NOT occur between aqueous solutions of

    CuSO4 and NaCl

  • 58

    The maximum number of electrons in the third electron shell of atoms is

    18

  • 59

    The rate of a chemical reaction Fe(s) + H2SO4(l) —>FeSO4(l) + H2(g) does NOTdepend on

    The pressure

  • 60

    From the fact that two aqueous solutions of glucose and sucrose have the same osmotic pressure, it can be concluded that the solutions are

    Isotonic

  • 61

    The mass of the solute and the mass of water in 150 g of an aqueous solution of potash (K2CO3) with a mass fraction of 5% are, respectively

    7,5g K2CO3 and 142,5g H2O

  • 62

    Two fructose solutions (1) and (2) have concentrations c1 and c2 such that of c1<c2. The boiling points(Tk1 and Tk2) of the solutions can be said that

    Tk1<Tk2

  • 63

    When AgNO3(l) is added to an aqueous solution, a white precipitate is obtained. This indicates the possible presence of.

    Cl- ions

  • 64

    Hydrogen is released during which reaction?

    Na(s) + HCl(l)

  • 65

    The kinetic equation of the reaction 2CO(g) + O2(g) —> 2CO2(g) + Q is

    v= k*c(CO)*c(O2)

  • 66

    During the hydrolysis of salts, heat is absorbed, which means that the process is

    Endothermic and the heat effect is denoted by -Q

  • 67

    If the pressure in the equilibrium system is lowered :CO2(g)+ C(s) —><— 2CO(g) -Q then

    c(CO)increases

  • 68

    If a salt crystal is placed in a glass of an aqueous salt solution and the size of the crystal does not change over time it can be concluded that the solution is

    Saturated

  • 69

    What is substance X in the transition Ca(HCO3)2–>X—>CaO?

    CaCO3

  • 70

    When the concentration of carbon monoxide doubles the rate of the chemical reaction 2CO(g)+ O2(g) —> 2CO2(g) +!Q

    Decreases

  • 71

    In which of the transitions is there a conversation that is NOT possible

    Cu—>CuO—>Cu(OH)2—>CuSO4

  • 72

    Solutions of sulphuric acid and dipotassium sulphate can be distinguished by

    The colour change of the litmus

  • 73

    Nitrogen is NOT characterised by interaction with

    Water

  • 74

    The simple substances of which of the listed chemical elements: A-Cooper, B-iron, C-silver D-aluminium, E-chrome, can react with concentrated sulphuric and nitric acid when heated?

    A and C

  • 75

    Which electron subshell in the lanthanides is NOT completely filled

    4f

  • 76

    Which of the following oxides is the only anhydride of nitric acid?

    N2O5

  • 77

    The basic salts are obtained after

    Incomplete neutralisation of multivalent bases

  • 78

    The acidic salts are obtained after

    Incomplete neutralisation of polybasic acids

  • 79

    In what container can an aqueous solution of nickel sulphate be stored

    Cooper

  • 80

    What is the reaction of the medium of the aqueous solution of the salt NH4Cl:

    Acidic

  • 81

    Specify the colour of the flame of potassium salt

    Violet

  • 82

    The hydrolysis constant (Kb) depends on:

    The temperature

  • 83

    Which of the numbers shown below has a value closest to the pH of a sodium base solution with a concentration of 10*-4 mol/l

    10.2

  • 84

    Which answer consists of salts whose aqueous solutions have a pH close to neutral?

    (NH4)2CO3, CH3COONH4

  • 85

    In the reaction: A+B+Q—><—C+D the formation of the products is accompanied by:

    Increase in temperature in the system

  • 86

    In the equilibrium system: N2(g)+3H2(g)—><—2NH3(g) at constant temperature

    c(N2), c(H2) and c(NH3) are permanent

  • 87

    At a given temperature a saturated solution can become unsaturated when:

    Solvent is added

  • 88

    In the reaction: SO2(g)+ 2H2S(g)—>3S(s)+2H2O(l) the oxidising agent is

    SO2

  • 89

    Which of the following interactions does NOT occur?

    Magnesium and caustic soda

  • 90

    The process of dissolving concentrated H2SO4 in water is:

    Exothermic- heat is released

  • 91

    The speed of a homogeneous catalytic process depends on:

    the concentration of the starting substances and of the catalyst

  • 92

    Which of the statements is false:

    According to the Bronsted-Lowry theory, bases contain hydroxide groups

  • 93

    What is the electric charge of the pellet?

    Coincides with the charge of the ions absorbed on the nucleus

  • 94

    Which of the reactions will not produce hydroxide:

    CuO + H2O —>

  • 95

    Which of the following statements is not true about catalysts:

    They change the heat effect of the reaction

  • 96

    The reaction products of an endothermic process:

    Are more unstable than the starting substances

  • 97

    In the presence of a catalyst, the chemical equilibrium shifts

    Does not shift

  • 98

    How can the value of the degree of electrolyte dissociation (a) be increased for a solution of the weak electrolyte CH3COONa:

    By adding water

  • 99

    The rate constant depends on:

    all of the above factors

  • 100

    Which of the following statements is not true?

    catalysts speed up chemical reactions only at high temperature