問題一覧
1
The electronic configuration of cu2+ ion is :The electronic configuration of cu2+ ion is :
3d9 4s0
2
Which is the correct order for the listed atoms with increase of the atomic radius :Which is the correct order for the listed atoms with increase of the atomic radius :
B , Be , Li , Na
3
A π-bond is the result of :A π-bond is the result of :
overlap of two p-orbitals
4
What is the ground electronic state of Mn 2+
1s2 2s2 2p6 3s2 3p6 3d5
5
The capability of alcohols to form intermolecular hydrogen bonds leads to:
decreased vapor pressure
6
Which is the correct order of halogen ions with decrease of reductive properties?
I- , Br-, Cl- , F-
7
The the element X has an atomic number of 8 and a mass number of 17. The atoms of this element contain :
9 neutrons
8
Which of the following elements exists as a monoatomic gas under standard conditions?
neon
9
Hydrogen may NOT be obtained by
interaction of cooper and nitric acid
10
The industrial process of production of sulphuric acid includes the following stages
production of SO2 , catalytic oxidation to SO3 and interaction of SO3 with water
11
Mark the line which includes only salts, whose water solutions are basic:
Sodium carbonate, potassium sulphide, potassium phosphate
12
Chlorine CANNOT be obtained
By interaction of sodium chloride with concentrated sulphuric acid
13
Increasing the pressure in an equilibrium system containing gas molecules leads to the withdrawal of the chemical equilibrium in the direction of the reaction
Flowing with decrease in the gas molecules number
14
At two fold increase of the pressure the rates of the straight and the reverse reaction of the system A(g) + 2B(g) = AB2(g) are changed accordingly
Straight -increased 8 times, reverse-increased 2 times
15
10 moles of benzene contain
6.02*10 *24 benzene molecules
16
In oxidative -reduction processes the reducer
Increases its oxidation number
17
In oxidative-reductive processes the oxidising agent
Decreases its oxidation number
18
Oxidative reductive processes could be
All answers are correct
19
The oxidation number for hydrogen in NaH is
-1
20
When nonspontaneous redox reactions occure by use of a direct electric current, the process is called
Electrolysis
21
The hydroxonium ion is represented as
H3O+
22
The chemical elements presented are arranged in order of decrease in their reactivity according to the activity series of metals. Ca , Na , Mg , Zn , Fe , H , Cu , Hg , Ag , Au Which is the best reducing agent ,which is oxidised the easiest?
Ca
23
The cathode in an electrochemical cell is the electrode that is
The electrode where reduction takes place
24
With addition of a catalyst to a system at equilibrium
The forward and reverse reactions rates are increased equally
25
The chemical reaction 2Cl2 + H2O —><—O2 + 4HCl is in chemical equilibrium. The rate of the forward reaction is
Equal to the rate of the reverse reaction
26
Hydrogen peroxide is easily decomposed to water and oxygen according to the reaction 2H2O2–> 2H2O + O2 . It’s ability is increased in the presence of H3PO4
H3PO4 negative Catalyst and the catalysis is homogenous
27
How many times the rate of the reaction 2NO + O2 —> 2NO2 will increase if the concentration of all substances is increased two times
8 times
28
The reaction rate of a multistage reaction is determined by
The rate of the slowest stage
29
The chemical elements of group IB have
1 electron in their outermost electronic shell
30
The isotopes
Occupy one and the same location in the periodic table of elements
31
The principal quantum number
All answers are correct
32
There azimuthal quantum number
All answers are correct
33
Finding the permitted states of electrons
Is done with the help of Pauli’s principal
34
Which statement for an equilibrium system is true?
The rate of the straight and reverse reaction are equal
35
The equilibrium constant of a given reaction depends on
The nature of the reactants and the temperature
36
Henry’s law is Is followed when
There is no chemical interaction between the dissolving gas and the solvent
37
The Tyndall effect is due to
Dispersion of the light
38
Indicate the wrong statement
The equilibrium constant depends on the presence of catalysts
39
How the degree of electrolyte dissociation(a) and the dissociation constant (KD)of solution of HCN will change upon increasing its concentration
a decreases, KD is not changed
40
The foam is a system of
Gas dispersed in liquid
41
If to an aqueous solution of HCN is added NaOH the degree of electrolyte dissociation (a) for HCN
Increases
42
What is the pH value of 0.01M solution of HCl
2
43
An aqueous solution of a salt has pH 9. Thus it follows that this is a salt of :
Weak acid and strong base
44
The maximal oxidation state of the atoms of chemical elements is equal to
The number of the group in which is the element in the periodic table
45
A colloid of Al(OH)3 with positively charged granules coagulates with the addition of a certain amount of electrolyte. Which of the listed electrolytes, on equal terms( concentration ,volume) will cause the fastest coagulation?
Al2(SO4)3
46
Which of the presented reactions is NOT oxidative-reductive ?
Interaction of calcium hydroxide with sulphuric acid
47
For manufacture of nitric acid two oxides are used :
NO and NO2
48
On combustion of ammonia, the nitrogen is converted to:
free N2
49
Which statement about the four quantum numbers which describe electrons in atoms is INCORRECT?
l= subsidiary (or azimuthal) quantum number, l=1,2,3,…,(n+1)
50
In reaction A has an activation energy of 250 kJ And reaction Bhas an activation energy of 100 kJ which of the following statements MUST be correct?
At the same temperature the rate of reaction B is greater than the rate of reaction A.
51
In which row against the type of the chemical bond is a suitable listed example?
Covalent polar, simple bond-H2O
52
The crystalline substance X is very soluble in water, it melts when heated, and its (aqueous solution does NOT conduct electricity. Substance X can be:
Glucose
53
In which pair of substances is the oxidation number of carbon -4 and +4, respectively?
CH4, CaCO3
54
Which of the following substances is the electrolyte?
CH3COOH
55
At constant temperature an aqueous solution of glucose with concentration of 1mol/L compared to water has
Higher osmotic pressure
56
In which of the indicated pairs there is NO correspondence between the chemical formula and the name of the substance?
Na2O2-disodium oxide
57
Interaction does NOT occur between aqueous solutions of
CuSO4 and NaCl
58
The maximum number of electrons in the third electron shell of atoms is
18
59
The rate of a chemical reaction Fe(s) + H2SO4(l) —>FeSO4(l) + H2(g) does NOTdepend on
The pressure
60
From the fact that two aqueous solutions of glucose and sucrose have the same osmotic pressure, it can be concluded that the solutions are
Isotonic
61
The mass of the solute and the mass of water in 150 g of an aqueous solution of potash (K2CO3) with a mass fraction of 5% are, respectively
7,5g K2CO3 and 142,5g H2O
62
Two fructose solutions (1) and (2) have concentrations c1 and c2 such that of c1<c2. The boiling points(Tk1 and Tk2) of the solutions can be said that
Tk1<Tk2
63
When AgNO3(l) is added to an aqueous solution, a white precipitate is obtained. This indicates the possible presence of.
Cl- ions
64
Hydrogen is released during which reaction?
Na(s) + HCl(l)
65
The kinetic equation of the reaction 2CO(g) + O2(g) —> 2CO2(g) + Q is
v= k*c(CO)*c(O2)
66
During the hydrolysis of salts, heat is absorbed, which means that the process is
Endothermic and the heat effect is denoted by -Q
67
If the pressure in the equilibrium system is lowered :CO2(g)+ C(s) —><— 2CO(g) -Q then
c(CO)increases
68
If a salt crystal is placed in a glass of an aqueous salt solution and the size of the crystal does not change over time it can be concluded that the solution is
Saturated
69
What is substance X in the transition Ca(HCO3)2–>X—>CaO?
CaCO3
70
When the concentration of carbon monoxide doubles the rate of the chemical reaction 2CO(g)+ O2(g) —> 2CO2(g) +!Q
Decreases
71
In which of the transitions is there a conversation that is NOT possible
Cu—>CuO—>Cu(OH)2—>CuSO4
72
Solutions of sulphuric acid and dipotassium sulphate can be distinguished by
The colour change of the litmus
73
Nitrogen is NOT characterised by interaction with
Water
74
The simple substances of which of the listed chemical elements: A-Cooper, B-iron, C-silver D-aluminium, E-chrome, can react with concentrated sulphuric and nitric acid when heated?
A and C
75
Which electron subshell in the lanthanides is NOT completely filled
4f
76
Which of the following oxides is the only anhydride of nitric acid?
N2O5
77
The basic salts are obtained after
Incomplete neutralisation of multivalent bases
78
The acidic salts are obtained after
Incomplete neutralisation of polybasic acids
79
In what container can an aqueous solution of nickel sulphate be stored
Cooper
80
What is the reaction of the medium of the aqueous solution of the salt NH4Cl:
Acidic
81
Specify the colour of the flame of potassium salt
Violet
82
The hydrolysis constant (Kb) depends on:
The temperature
83
Which of the numbers shown below has a value closest to the pH of a sodium base solution with a concentration of 10*-4 mol/l
10.2
84
Which answer consists of salts whose aqueous solutions have a pH close to neutral?
(NH4)2CO3, CH3COONH4
85
In the reaction: A+B+Q—><—C+D the formation of the products is accompanied by:
Increase in temperature in the system
86
In the equilibrium system: N2(g)+3H2(g)—><—2NH3(g) at constant temperature
c(N2), c(H2) and c(NH3) are permanent
87
At a given temperature a saturated solution can become unsaturated when:
Solvent is added
88
In the reaction: SO2(g)+ 2H2S(g)—>3S(s)+2H2O(l) the oxidising agent is
SO2
89
Which of the following interactions does NOT occur?
Magnesium and caustic soda
90
The process of dissolving concentrated H2SO4 in water is:
Exothermic- heat is released
91
The speed of a homogeneous catalytic process depends on:
the concentration of the starting substances and of the catalyst
92
Which of the statements is false:
According to the Bronsted-Lowry theory, bases contain hydroxide groups
93
What is the electric charge of the pellet?
Coincides with the charge of the ions absorbed on the nucleus
94
Which of the reactions will not produce hydroxide:
CuO + H2O —>
95
Which of the following statements is not true about catalysts:
They change the heat effect of the reaction
96
The reaction products of an endothermic process:
Are more unstable than the starting substances
97
In the presence of a catalyst, the chemical equilibrium shifts
Does not shift
98
How can the value of the degree of electrolyte dissociation (a) be increased for a solution of the weak electrolyte CH3COONa:
By adding water
99
The rate constant depends on:
all of the above factors
100
Which of the following statements is not true?
catalysts speed up chemical reactions only at high temperature